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Issue 19, 2000
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Structural characterisation of basic zinc O,O ′-dialkyl dithiophosphosphate and two isomeric examples of zinc monothiophosphates

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Abstract

The crystal structure of basic Zn4O[S2P(OBui)2]6 revealed a Zn4O core. Two examples of zinc monothiophosphates, Zn4[O(S)P(OPh)2]6O and Zn4[O(S)P(OMe)2]6O, have also been synthesized and structurally characterised. These systems also contain a Zn4O core but display an interesting isomerism as a consequence of the unsymmetrical O,S donor ligands.

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Article information


Submitted
16 May 2000
Accepted
10 Jul 2000
First published
11 Sep 2000

J. Chem. Soc., Dalton Trans., 2000, 3269-3273
Article type
Paper

Structural characterisation of basic zinc O,O ′-dialkyl dithiophosphosphate and two isomeric examples of zinc monothiophosphates

S. Menzer, J. R. Phillips, A. M. Z. Slawin, D. J. Williams and J. D. Woollins, J. Chem. Soc., Dalton Trans., 2000, 3269
DOI: 10.1039/B003915M

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