Issue 21, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Copper(I) dicyanamide coordination polymers: ladders, sheets, layers, diamond-like networks and unusual interpenetration †

Stuart R. Batten,*a   Alexander R. Harris,a   Paul Jensen,a   Keith S. Murraya  and  Angela Ziebella  

* Corresponding authors

a Department of Chemistry, Monash University 3800, PO Box 23, Australia
E-mail: stuart.batten@sci.monash.edu.au
Fax: +61-3-9905-4597

Abstract

The structures of six new derivatives of copper(I) dicyanamide (dicyanamide = N(CN)2−, dca) have been determined. Those of Cu(dca)(MeCN) 1 and Cu(dca)(Me4pyz)1/22, Me4pyz = tetramethylpyrazine, both contain (6,3) sheets. Cu2(dca)2(bipy)(MeCN)2·0.5bipy 3, bipy = 4,4′-bipyridine, consists of 1-D ladder-like polymers with intercalated bipy guests. Cu4(dca)4(bipy)3(MeCN)24 is composed of 2-D layers which each interpenetrate with four others in a parallel fashion, resulting in a novel 3-D interlocking of layers. α-Cu(dca)(bpe) 5, bpe = 1,2-bis(4-pyridyl)ethene, consists of 2-D (4,4) sheets displaying twofold parallel interpenetration, while β-Cu(dca)(bpe) 6 contains five diamond-like networks which interpenetrate in an unprecedented fashion.

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Article information

DOI
https://doi.org/10.1039/B003527K
Article type
Paper
Submitted
03 May 2000
Accepted
06 Jun 2000
First published
25 Sep 2000

J. Chem. Soc., Dalton Trans., 2000, 3829-3836

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Copper(I) dicyanamide coordination polymers: ladders, sheets, layers, diamond-like networks and unusual interpenetration

S. R. Batten, A. R. Harris, P. Jensen, K. S. Murray and A. Ziebell, J. Chem. Soc., Dalton Trans., 2000, 3829 DOI: 10.1039/B003527K

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