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Issue 22, 1998
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Synthesis of a base-stabilized alumoxane: preferential hydrolysis of an aluminium–amido over an aluminium–alkyl

Abstract

The preferential hydrolytic cleavage of an A1-N versus an A1-C bond allows for isolation of the base stabilized alkylalumoxane,[(tBu)2A1{NH(Me)CH2CH2NMe2}]2(µ-O), from the hydrolysisof the intra-molecularly stabilized amino-amide compound, (tBu)2A1[N(Me)CH2CH2NMe2], providing a possible general route to alkylalumoxanes.

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Article type: Paper
DOI: 10.1039/A806502K
J. Chem. Soc., Dalton Trans., 1998, 3703-3704

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    Synthesis of a base-stabilized alumoxane: preferential hydrolysis of an aluminium–amido over an aluminium–alkyl

    C. Niamh McMahon and A. R. Barron, J. Chem. Soc., Dalton Trans., 1998, 3703
    DOI: 10.1039/A806502K

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