Issue 22, 1998
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis of a base-stabilized alumoxane: preferential hydrolysis of an aluminium–amido over an aluminium–alkyl

C. Niamh McMahon  and  Andrew R. Barron  

Abstract

The preferential hydrolytic cleavage of an A1-N versus an A1-C bond allows for isolation of the base stabilized alkylalumoxane,[(tBu)2A1{NH(Me)CH2CH2NMe2}]2(µ-O), from the hydrolysisof the intra-molecularly stabilized amino-amide compound, (tBu)2A1[N(Me)CH2CH2NMe2], providing a possible general route to alkylalumoxanes.

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Article information

DOI
https://doi.org/10.1039/A806502K
Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 3703-3704

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Synthesis of a base-stabilized alumoxane: preferential hydrolysis of an aluminium–amido over an aluminium–alkyl

C. Niamh McMahon and A. R. Barron, J. Chem. Soc., Dalton Trans., 1998, 3703 DOI: 10.1039/A806502K

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