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Issue 12, 1995
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Dalton communications. Synthesis and structural characterisation of [Pd43-CH)(µ-Cl)3(PBut3)4]: a tetrahedral palladium cluster with a µ3-methylidyne ligand

Abstract

The compound [Pd43-CH)(µ-Cl)3(PBut3)4] has been synthesised from [Pd2(dba)3](dba = dibenzylideneacetone), PBut3 and CHCl3 and characterised spectroscopically and by single-crystal X-ray analysis; it undergoes substitution reactions with Br and tertiary phosphines and is a catalyst for the polymerisation of ethyne.

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Article type: Paper
DOI: 10.1039/DT9950002107
Citation: J. Chem. Soc., Dalton Trans., 1995,0, 2107-2108

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    Dalton communications. Synthesis and structural characterisation of [Pd43-CH)(µ-Cl)3(PBut3)4]: a tetrahedral palladium cluster with a µ3-methylidyne ligand

    A. D. Burrows, D. M. P. Mingos, S. Menzer, R. Vilar and D. J. Williams, J. Chem. Soc., Dalton Trans., 1995, 0, 2107
    DOI: 10.1039/DT9950002107

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