Issue 8, 1994

Dalton communications. New co-ordination mode of 4,5-dimercapto-1,3-dithiole-2-thionate(2–) in polynuclear gold(I) complexes. Crystal structures of [Au33-C3S5)(PPh3)3] ClO4 and [Au4(µ-C3S5)2(µ-Ph2PCH2PPh2)2]

Abstract

The ligand 4,5-dimercapto-1,3-dithiole-2-thionate(2–)(C3S52–) has been transferred from [Net4]2-[Zn(C3S5)2] to gold(I) centres, affording di-, tri- or tetra-nuclear complexes containing the C3S52– ligand in unprecedented µ- or µ3-bridging forms.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 1325-1326

Dalton communications. New co-ordination mode of 4,5-dimercapto-1,3-dithiole-2-thionate(2–) in polynuclear gold(I) complexes. Crystal structures of [Au33-C3S5)(PPh3)3] ClO4 and [Au4(µ-C3S5)2(µ-Ph2PCH2PPh2)2]

E. Cerrada, A. Laguna, M. Laguna and P. G. Jones, J. Chem. Soc., Dalton Trans., 1994, 1325 DOI: 10.1039/DT9940001325

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