Issue 12, 1986
From the journal:

Journal of the Chemical Society, Dalton Transactions

A general route for the synthesis of tetranuclear clusters containing closed triruthenium and triosmium triangles

Gary A. Foulds,   Brian F. G. Johnson,   Jack Lewis  and  Robert M. Sorrell  

Abstract

The cluster compounds [N(PPh3)2][M3M′(CO)13](M = Ru or Os, M′= Co) and [N(PPh3)2][M3M′H(CO)13](M = Ru or Os; M′= Fe, Ru, or Os) have been prepared in good yield by the reaction of an appropriate tetracarbonylmetalate with the bis(acetonitrile) complexes, [M3(CO)10(NCMe)2](M = Ru or Os). The anionic clusters have been protonated, where possible, to give the corresponding neutral hydride clusters. In addition to known tetranuclear clusters synthesised by this method, we report the new cluster compounds [N(PPh3)2][Os3RuH(CO)13], [N(PPh3)2][Ru3OsH(CO)13], and [Ru3OsH2(CO)13].

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Article information

DOI
https://doi.org/10.1039/DT9860002515
Article type
Paper

J. Chem. Soc., Dalton Trans., 1986, 2515-2518

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A general route for the synthesis of tetranuclear clusters containing closed triruthenium and triosmium triangles

G. A. Foulds, B. F. G. Johnson, J. Lewis and R. M. Sorrell, J. Chem. Soc., Dalton Trans., 1986, 2515 DOI: 10.1039/DT9860002515

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