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Issue 6, 1986
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The anion of pyrimidine-2-thiol as a ligand to molybdenum, tungsten, and iron. Preparation of complexes, their structure and reactivity

Abstract

The syntheses and structures of [FeL3] and [MoL4] are described (L = pyrimidine-2-thiolate). The structures are similar to those of the known Co and W homologous complexes. The unbound nitrogens can be cleanly protonated and alkylated, but they are weak donors to Lewis acids such as Fe and Cu.

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Article type: Paper
DOI: 10.1039/DT9860001181
Citation: J. Chem. Soc., Dalton Trans., 1986,0, 1181-1187

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    The anion of pyrimidine-2-thiol as a ligand to molybdenum, tungsten, and iron. Preparation of complexes, their structure and reactivity

    I. A. Latham, G. J. Leigh, C. J. Pickett, G. Huttner, I. Jibrill and J. Zubieta, J. Chem. Soc., Dalton Trans., 1986, 0, 1181
    DOI: 10.1039/DT9860001181

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