Issue 9, 1985
From the journal:

Journal of the Chemical Society, Dalton Transactions

Thermodynamic treatment of exchange of H+ and K+ in α-titanium phosphate

Carmen G. Guarido,   Marta Suárez,   José R. García  and  Julio Rodríguez  

Abstract

The H+/K+ ion-exchange process in α-titanium phosphate, Ti(HPO4)2·H2O, was studied, titration curves and exchange isotherms being obtained at 25.0, 40.0, and 55.0 (± 0.1)°C. Partial decomposition of the exchanger was detected. No partially substituted phases were detected by X-ray diffraction and the final product was Ti(KPO4)2·3H2O. The free energy, enthalpy, and entropy for the exchange reaction are determined, and the results are explained by means of structural considerations.

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Article information

DOI
https://doi.org/10.1039/DT9850001865
Article type
Paper

J. Chem. Soc., Dalton Trans., 1985, 1865-1867

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Thermodynamic treatment of exchange of H+ and K+ in α-titanium phosphate

C. G. Guarido, M. Suárez, J. R. García and J. Rodríguez, J. Chem. Soc., Dalton Trans., 1985, 1865 DOI: 10.1039/DT9850001865

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