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Issue 4, 1983
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Matrix isolation studies of the bonding of acetyl groups in the co-ordinatively unsaturated species acetyltetracarbonylmanganese and acetylmonocarbonyl(η-cyclopentadienyl)iron

Abstract

The infrared band positions of νCO(acetyl) for [Mn(CO)4(COCH3)] and [Fe(η5-C5H5)(CO)(COCH3)] are reported in CH4 matrices at 12 K. It is proposed that the acetyl ligands have σ-acetyl type bonding in these co-ordinatively unsaturated species.

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Article information


J. Chem. Soc., Dalton Trans., 1983, 615-618
Article type
Paper

Matrix isolation studies of the bonding of acetyl groups in the co-ordinatively unsaturated species acetyltetracarbonylmanganese and acetylmonocarbonyl(η-cyclopentadienyl)iron

R. B. Hitam, R. Narayanaswamy and A. J. Rest, J. Chem. Soc., Dalton Trans., 1983, 615
DOI: 10.1039/DT9830000615

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