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Issue 9, 1981
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Crystal and molecular structures of the isobutene insertion product of endo-hexafluoroacetylacetonato(methoxytetraphenylbutadienyl)-palladium(II)

Abstract

X-Ray analysis shows crystals of the title compound to be monoclinic, space group P21/c, with cell dimensions a= 19.680(7), b= 12.470(6), c= 17.532(7)Å, β= 118.9(1)°, Z= 4. The complex has the structure assigned to it (on the basis of several physical techniques) except for the stereochemistry of the PhC[double bond, length half m-dash]CPhOMe group which is unexpectedly cis-diphenyl. The crystal contains one molecule of n-pentane of crystallization per two molecules of complex.

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J. Chem. Soc., Dalton Trans., 1981, 1935-1937
Article type
Paper

Crystal and molecular structures of the isobutene insertion product of endo-hexafluoroacetylacetonato(methoxytetraphenylbutadienyl)-palladium(II)

W. Wong-Ng and S. C. Nyburg, J. Chem. Soc., Dalton Trans., 1981, 1935
DOI: 10.1039/DT9810001935

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