Jump to main content
Jump to site search

Issue 8, 1981
Previous Article Next Article

Co-ordination properties of N-protected amino-acids. Solution and solid-state behaviour of bis(benzyloxycarbonyl-L-tryptophanato)-nickel(II) and its mixed complexes

Abstract

Polarographic measurements show that nickel(II) ion and benzyloxycarbonyl-L-tryptophan (Z-L-tryptophan) form complexes in methanol with 1 : 2 and 1 : 4 metal-to-ligand ratios, depending on the ligand concentration. A complete scheme of the reactions which take place in solution and at the electrode is proposed. The 1 : 2 complex [NiL2]·2H2O and some amine adducts have been obtained in the solid state. In the solids the amino-acid is co-ordinated only through the carboxylate group.

Back to tab navigation

Article information


J. Chem. Soc., Dalton Trans., 1981, 1665-1668
Article type
Paper

Co-ordination properties of N-protected amino-acids. Solution and solid-state behaviour of bis(benzyloxycarbonyl-L-tryptophanato)-nickel(II) and its mixed complexes

R. Battini, G. G. Battistuzzi, G. Grandi, L. Menabue, G. C. Pellacani, M. Saladini and A. B. Corradi, J. Chem. Soc., Dalton Trans., 1981, 1665 DOI: 10.1039/DT9810001665

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.


Search articles by author

Spotlight

Advertisements