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Issue 7, 1981
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The structures and fluxional behaviour of the binary carbonyls; a new approach. Part 3. The fluxional behaviour of [Fe3(CO)11L], L = PR3 or P(OR)3

Abstract

The stereodynamic behaviour of the complexes [Fe3(CO)11L][L = PR3 or P(OR)3], as determined by 13C n.m.r. spectroscopy over a wide temperature range, has been interpreted in terms of an icosahedral cube-octahedral interchange of ligands of the type previously postulated for [M4(CO)12](M = Co, Rh, or lr) and their derivatives.

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Article information


J. Chem. Soc., Dalton Trans., 1981, 1535-1539
Article type
Paper

The structures and fluxional behaviour of the binary carbonyls; a new approach. Part 3. The fluxional behaviour of [Fe3(CO)11L], L = PR3 or P(OR)3

R. E. Benfield, P. D. Gavens, B. F. G. Johnson, M. J. Mays, S. Aime, L. Milone and D. Osella, J. Chem. Soc., Dalton Trans., 1981, 1535
DOI: 10.1039/DT9810001535

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