Issue 15, 1977
From the journal:

Journal of the Chemical Society, Dalton Transactions

Structure and bonding in gold(I) compounds. Part 1. The trans influence in linear complexes

Peter G. Jones  and  Alan F. Williams  

Abstract

The trans influence in linear gold(I) complexes [AuClL] has been studied by 35Cl n.q.r. spectroscopy [L = RNC (R = Ph, p-MeOC6H4, or C6H11), Cl–, C5H5N, PR′3(R′= Et, Ph, C6H11, Cl, OMe, or OPh), AsPh3, PPh3S, or SMe2]. The 35Cl n.q.r. frequencies show a high senstitvity to the trans ligand, and may be related to the bonding properties of this ligand. It is concluded that σ-bonding effects are dominant. The results are significantly different from those obtained from similar studies of square-planar platinum(II) complexes.

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Article information

DOI
https://doi.org/10.1039/DT9770001430
Article type
Paper

J. Chem. Soc., Dalton Trans., 1977, 1430-1434

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Structure and bonding in gold(I) compounds. Part 1. The trans influence in linear complexes

P. G. Jones and A. F. Williams, J. Chem. Soc., Dalton Trans., 1977, 1430 DOI: 10.1039/DT9770001430

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