SCHEDULED MAINTENANCE
Co-ordinates and “vibrationally-adiabatic” approximations are described for reactions in three dimensions. Some reactions may demonstrate a fairly strict adiabaticity for certain degrees of freedom and a statistical adiabaticity for others. Some will simply be strongly vibrationally-nonadiabatic. Several topics in kinetics are considered from the viewpoint of vibrational-adiabaticity or mild non-adiabaticity.
R. A. Marcus, Discuss. Faraday Soc., 1967, 44, 7 DOI: 10.1039/DF9674400007
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