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Issue 13, 2016
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Removing the superfluous: a supported squaramide catalyst with a minimalistic linker applied to the enantioselective flow synthesis of pyranonaphthoquinones

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Abstract

A continuous flow setup has been implemented for the enantioselective production of a library of pyranonaphthoquinones. This was possible through a sequential two-step process involving a squaramide-catalyzed Michael reaction and oxa-Michael cyclization. A key factor for the success of this methodology was the development of a new, cost-effective polystyrene-supported squaramide.

Graphical abstract: Removing the superfluous: a supported squaramide catalyst with a minimalistic linker applied to the enantioselective flow synthesis of pyranonaphthoquinones

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Article information


Submitted
03 Mar 2016
Accepted
18 Mar 2016
First published
21 Mar 2016

Catal. Sci. Technol., 2016,6, 4686-4689
Article type
Communication
Author version available

Removing the superfluous: a supported squaramide catalyst with a minimalistic linker applied to the enantioselective flow synthesis of pyranonaphthoquinones

L. Osorio-Planes, C. Rodríguez-Escrich and M. A. Pericàs, Catal. Sci. Technol., 2016, 6, 4686
DOI: 10.1039/C6CY00473C

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