Issue 13, 2016
From the journal:

Catalysis Science & Technology

Integration of borylation of aryllithiums and Suzuki–Miyaura coupling using monolithic Pd catalyst†

A. Nagaki,*a   K. Hirose,a   Y. Moriwaki,a   K. Mitamura,b   K. Matsukawa,b   N. Ishizukac  and  J. Yoshida*a  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615–8510, Japan
E-mail: anagaki@sbchem.kyoto-u.ac.jp, yoshida@sbchem.kyoto-u.ac.jp

b Emaus Kyoto Inc. R&Ds, 26 Nishida-cho, Saiin, Ukyo-ku, Kyoto 615–0055, Japan

c Osaka Municipal Technical Research Institute, Electronic Material Research Division, 1-6-50, Morinomiya, Joto-ku, Osaka 536–8553, Japan

Abstract

Integration of the preparation of arylboronic esters via aryllithiums and Suzuki–Miyaura coupling using monolithic Pd catalyst without an intentionally added base was achieved. A continuous operation has been done successfully for over 21 hours.

Graphical abstract: Integration of borylation of aryllithiums and Suzuki–Miyaura coupling using monolithic Pd catalyst

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Article information

DOI
https://doi.org/10.1039/C5CY02098K
Article type
Communication
Submitted
04 Dec 2015
Accepted
05 Jan 2016
First published
19 Jan 2016

Catal. Sci. Technol., 2016,6, 4690-4694

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Integration of borylation of aryllithiums and Suzuki–Miyaura coupling using monolithic Pd catalyst

A. Nagaki, K. Hirose, Y. Moriwaki, K. Mitamura, K. Matsukawa, N. Ishizuka and J. Yoshida, Catal. Sci. Technol., 2016, 6, 4690 DOI: 10.1039/C5CY02098K

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