Issue 1, 2015
From the journal:

Catalysis Science & Technology

Novel iron(iii) catalyst for the efficient and selective coupling of carbon dioxide and epoxides to form cyclic carbonates†

Antonio Buonerba,ab   Assunta De Nisi,a   Alfonso Grassi,ab   Stefano Milione,ab   Carmine Capacchione,*ab   Sergei Vaginc  and  Bernhard Riegerc  

* Corresponding authors

a Dipartimento di Chimica e Biologia, Università degli Studi di Salerno, via Giovanni Paolo II, 132-84084 Fisciano (SA), Italy
E-mail: ccapacchione@unisa.it

b NANOMATES, Research Centre for NANOMAterials and nanoTEchnology at Salerno University, 84084 Fisciano (SA), Italy

c WACKER Lehrstuhl für Makromolekulare Chemie, Technische Universität München, Lichtenbergstrasse 4, 85748 Garching, Germany

Abstract

“Re-cycling carbon dioxide with iron”. The synthesis of cyclic organic carbonates in high yield, stereo- and chemo-selectivity was accomplished through the coupling of carbon dioxide and epoxides, catalysed by a novel air-stable and easy-to-handle thioether-triphenolate iron(III) complex.

Graphical abstract: Novel iron(iii) catalyst for the efficient and selective coupling of carbon dioxide and epoxides to form cyclic carbonates

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Article information

DOI
https://doi.org/10.1039/C4CY01187B
Article type
Communication
Submitted
13 Sep 2014
Accepted
07 Oct 2014
First published
08 Oct 2014

Catal. Sci. Technol., 2015,5, 118-123

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Novel iron(III) catalyst for the efficient and selective coupling of carbon dioxide and epoxides to form cyclic carbonates

A. Buonerba, A. De Nisi, A. Grassi, S. Milione, C. Capacchione, S. Vagin and B. Rieger, Catal. Sci. Technol., 2015, 5, 118 DOI: 10.1039/C4CY01187B

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