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Issue 1, 2014
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Efficient H2 generation from formic acid using azole complexes in water

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Abstract

Iridium azole-containing complexes are demonstrated to catalyze the dehydrogenation of formic acid into H2–CO2 (1/1) mixtures in aqueous solution in the absence of organic additives, and with a maximum turnover frequency (TOF) of 34 000 h−1 at 80 °C.

Graphical abstract: Efficient H2 generation from formic acid using azole complexes in water

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Submitted
22 Oct 2013
Accepted
22 Oct 2013
First published
23 Oct 2013

Catal. Sci. Technol., 2014,4, 34-37
Article type
Communication

Efficient H2 generation from formic acid using azole complexes in water

Y. Manaka, W. Wang, Y. Suna, H. Kambayashi, J. T. Muckerman, E. Fujita and Y. Himeda, Catal. Sci. Technol., 2014, 4, 34
DOI: 10.1039/C3CY00830D

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