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Issue 1, 2014
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Efficient H2 generation from formic acid using azole complexes in water

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Abstract

Iridium azole-containing complexes are demonstrated to catalyze the dehydrogenation of formic acid into H2–CO2 (1/1) mixtures in aqueous solution in the absence of organic additives, and with a maximum turnover frequency (TOF) of 34 000 h−1 at 80 °C.

Graphical abstract: Efficient H2 generation from formic acid using azole complexes in water

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Publication details

The article was received on 22 Oct 2013, accepted on 22 Oct 2013 and first published on 23 Oct 2013


Article type: Communication
DOI: 10.1039/C3CY00830D
Catal. Sci. Technol., 2014,4, 34-37

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    Efficient H2 generation from formic acid using azole complexes in water

    Y. Manaka, W. Wang, Y. Suna, H. Kambayashi, J. T. Muckerman, E. Fujita and Y. Himeda, Catal. Sci. Technol., 2014, 4, 34
    DOI: 10.1039/C3CY00830D

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