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Issue 12, 2013
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Cyclopentadienyl N-heterocyclic carbene–nickel complexes as efficient pre-catalysts for the hydrosilylation of imines

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Abstract

The in situ generated nickel hydride complex, [Ni(Mes2NHC)HCp], and its cationic analogue, [Ni(Mes2NHC)(NCMe)Cp](PF6), are efficient and chemoselective pre-catalysts for the hydrosilylation of both aldimines and ketimines under mild conditions.

Graphical abstract: Cyclopentadienyl N-heterocyclic carbene–nickel complexes as efficient pre-catalysts for the hydrosilylation of imines

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Publication details

The article was received on 17 Jul 2013, accepted on 10 Sep 2013 and first published on 10 Sep 2013


Article type: Communication
DOI: 10.1039/C3CY00514C
Catal. Sci. Technol., 2013,3, 3111-3116

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    Cyclopentadienyl N-heterocyclic carbene–nickel complexes as efficient pre-catalysts for the hydrosilylation of imines

    L. P. Bheeter, M. Henrion, M. J. Chetcuti, C. Darcel, V. Ritleng and J. Sortais, Catal. Sci. Technol., 2013, 3, 3111
    DOI: 10.1039/C3CY00514C

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