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Issue 3, 2013
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Direct C–H bond arylations and alkenylations with phenol-derived fluorine-free electrophiles

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Abstract

Significant progress has been accomplished in direct C–H bond arylations of arenes and heteroarenes with readily accessible, inexpensive phenol derivatives. Thus, ruthenium biscarboxylate complexes and inexpensive cobalt compounds allowed for challenging C–H bond derivatizations of arenes. Further, palladium, nickel and cobalt catalysts set the stage for step-economical C–H/C–O bond functionalization with electron-rich as well as electron-deficient heteroarenes.

Graphical abstract: Direct C–H bond arylations and alkenylations with phenol-derived fluorine-free electrophiles

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Publication details

The article was received on 18 Jul 2012, accepted on 29 Sep 2012 and first published on 24 Oct 2012


Article type: Minireview
DOI: 10.1039/C2CY20505J
Catal. Sci. Technol., 2013,3, 562-571

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    Direct C–H bond arylations and alkenylations with phenol-derived fluorine-free electrophiles

    S. I. Kozhushkov, H. K. Potukuchi and L. Ackermann, Catal. Sci. Technol., 2013, 3, 562
    DOI: 10.1039/C2CY20505J

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