Issue 2, 2012
From the journal:

Catalysis Science & Technology

Amination and dehydration of 1,3-propanediol by hydrogen transfer: reactions of a bio-renewable platform chemical†

Sophie D. Lacroix,a   Annie Pennycook,a   Shifang Liu,a   Thomas T. Eisenharta  and  Andrew C. Marr*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Queen's University Belfast, David Keir Building, Belfast, UK
E-mail: a.marr@qub.ac.uk
Fax: +44 (0)28 9097 6524
Tel: +44 (0)28 9097 4442

Abstract

1,3-propanediol was subjected to a range of amination conditions. The N-heterocyclic carbene piano stool complex [Cp*IrCl2(bmim)] was found to be a good catalyst for amination and dehydration in toluene or ionic liquid; product compositions could be tuned by altering the ratio of diol to amine.

Graphical abstract: Amination and dehydration of 1,3-propanediol by hydrogen transfer: reactions of a bio-renewable platform chemical

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Article information

DOI
https://doi.org/10.1039/C1CY00339A
Article type
Communication
Submitted
25 Aug 2011
Accepted
25 Sep 2011
First published
17 Oct 2011

Catal. Sci. Technol., 2012,2, 288-290

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Amination and dehydration of 1,3-propanediol by hydrogen transfer: reactions of a bio-renewable platform chemical

S. D. Lacroix, A. Pennycook, S. Liu, T. T. Eisenhart and A. C. Marr, Catal. Sci. Technol., 2012, 2, 288 DOI: 10.1039/C1CY00339A

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