This review covers free radical additions, which are initiated by the formal addition of a hydrogen atom to a C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
C double bond. These reactions originated in the realms of inorganic chemistry, polymer chemistry, and organic chemistry, whereby barriers between these disciplines impeded the rapid implementation of the findings.
R. W. Hoffmann, Chem. Soc. Rev., 2016, 45, 577 DOI: 10.1039/C5CS00423C
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