Enhancing the sensitivity of a Nd3+,Yb3+:YVO4 nanocrystalline luminescent thermometer by host sensitization

Abstract

Numerous methods are known to improve the relative temperature sensitivity of luminescent thermometers. These methods include optimization of the host material, the size of the nanoparticles, the dopant ion type and concentration, or the excitation intensity and operation mode of the excitation source. Here we propose a new approach, which exploits temperature dependent host sensitized emission from Nd³⁺ and Yb³⁺ lanthanide ions in a YVO₄ matrix. We found out that the emission ratio of these two activators strongly depends on temperature, the size of the nanocrystals and the relative dopant concentration. The novelty comes from the fact that CT → Nd³⁺ and CT → Yb³⁺ are temperature dependent, and therefore helps to double the relative temperature sensitivity from ∼0.12% K⁻¹ up to 0.25% K⁻¹ for the smallest nanocrystals. Based on the temperature dependent luminescence lifetimes of Nd³⁺ and Yb³⁺ activators, we also found out that Nd³⁺ → Yb³⁺ ET has 70–75% efficiency and is temperature dependent.