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Issue 19, 2019
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Interfacially driven transport theory: a way to unify Marangoni and osmotic flows

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Abstract

We show that the solvent behaviour in both diffusio-osmosis and Marangoni flow can be derived from a simple model of colloid–interface interactions. We demonstrate that the direction of the flow is regulated by a single value of the attractive parameter covering the purely repulsive and attractive–repulsive interaction cases. The proposed universality between diffusio-osmosis and Marangoni flow is extended further to include diffusio-phoresis. In particular, an object immersed to a colloidal solution moves towards the low concentration of the colloidal particles in the case of colloid–interface repulsion and towards the high concentration of the colloidal particles in the case of colloid–interface attraction. The approach combines the methods of fluid dynamics, molecular physics and transport phenomena and provides a tractable explanation of how the colloid–interface interactions affect the momentum balance and the transport phenomena (interfacially driven transport).

Graphical abstract: Interfacially driven transport theory: a way to unify Marangoni and osmotic flows

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Publication details

The article was received on 19 Feb 2019, accepted on 29 Apr 2019 and first published on 29 Apr 2019


Article type: Paper
DOI: 10.1039/C9CP00999J
Phys. Chem. Chem. Phys., 2019,21, 10114-10124

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    Interfacially driven transport theory: a way to unify Marangoni and osmotic flows

    P. Bacchin, K. Glavatskiy and V. Gerbaud, Phys. Chem. Chem. Phys., 2019, 21, 10114
    DOI: 10.1039/C9CP00999J

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