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Issue 45, 2018
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Edge morphology induced rectifier diode effect in C3N nanoribbon

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The two-dimensional material C3N has a honeycomb structure similar to graphene, but its heterogeneity of carbon and nitrogen elements makes it multifunctional. By performing a first-principles study, we find that edge morphology induces interesting electronic transport properties in step-like heterojunction devices composed of width-variable zigzag C3N nanoribbons. As long as the right part has an edge of all-carbon morphology, negative differential resistance and rectification effects will occur. If both edges are not of all-carbon morphology due to the presence of N atoms, a forward-conducting and reverse-blocking rectifier diode behavior will appear. These phenomena originate from the peculiar electronic structure of the zigzag C3N nanoribbons. The number of energy bands crossing the Fermi level gradually decreases from 2 to 0 as the number of all-carbon edges decreases, realizing a transition from metal to semiconductor. The band gap determines the cut-off region at low bias and the presence of an interface barrier causes the cut-off state to continue under high reverse bias. Diverse edge morphologies, simple cutting methods and rich electronic transport properties make C3N materials competitive in nanodevice applications.

Graphical abstract: Edge morphology induced rectifier diode effect in C3N nanoribbon

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Supplementary files

Article information

15 Aug 2018
23 Oct 2018
First published
24 Oct 2018

Phys. Chem. Chem. Phys., 2018,20, 28759-28766
Article type

Edge morphology induced rectifier diode effect in C3N nanoribbon

J. He, Y. Guo, X. Yan and H. Zeng, Phys. Chem. Chem. Phys., 2018, 20, 28759
DOI: 10.1039/C8CP05209C

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