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Issue 40, 2018
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A one-dimensional solid-state NMR approach for 14NH/14NH overtone correlation through 1H/1H mixing under fast MAS

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Abstract

Homonuclear correlations are key to structural studies using solid-state NMR. In this contribution, using 14N overtone transition (OT) as a selective excitation approach, we propose a proton-detected one-dimensional (1D) 14NOT/14NOT/1H correlation solid-state NMR method mediated through 1H/1H mixing at fast magic angle spinning to achieve NH/NH proximities in naturally abundant samples. The proposed method is time efficient by a factor of ∼7.5 in comparison to the existing fundamental 14N frequency-based three-dimensional (3D) 14N/14N/1H correlation method.

Graphical abstract: A one-dimensional solid-state NMR approach for 14NH/14NH overtone correlation through 1H/1H mixing under fast MAS

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Publication details

The article was received on 06 Aug 2018, accepted on 27 Sep 2018 and first published on 28 Sep 2018


Article type: Paper
DOI: 10.1039/C8CP05000G
Citation: Phys. Chem. Chem. Phys., 2018,20, 25849-25853

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    A one-dimensional solid-state NMR approach for 14NH/14NH overtone correlation through 1H/1H mixing under fast MAS

    M. K. Pandey and Y. Nishiyama, Phys. Chem. Chem. Phys., 2018, 20, 25849
    DOI: 10.1039/C8CP05000G

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