Issue 1, 2015

Electronic effects of ligand substitution on metal–organic framework photocatalysts: the case study of UiO-66

Abstract

UiO-66-X (X = H, NH2, NO2, Br) have been successfully synthesized and tested for their photocatalytic activity in water treatment. Results show that electronic effect of the ligand substituents greatly affects the photocatalytic activity of UiO-66. The rates obtained by different substituents are linearly correlated with their Hammett coefficients.

Graphical abstract: Electronic effects of ligand substitution on metal–organic framework photocatalysts: the case study of UiO-66

Supplementary files

Article information

Article type
Communication
Submitted
16 Sep 2014
Accepted
30 Oct 2014
First published
03 Nov 2014

Phys. Chem. Chem. Phys., 2015,17, 117-121

Electronic effects of ligand substitution on metal–organic framework photocatalysts: the case study of UiO-66

L. Shen, R. Liang, M. Luo, F. Jing and L. Wu, Phys. Chem. Chem. Phys., 2015, 17, 117 DOI: 10.1039/C4CP04162C

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