Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 30, 2014
Previous Article Next Article

Constraints to the flat band potential of hematite photo-electrodes

Author affiliations

Abstract

We revisit the fundamental constraints that apply to flat band potential values at semiconductor photo-electrodes. On the physical scale, the Fermi level energy of a non-degenerate semiconductor at the flat band condition, EF(FB), is constrained to a position between the conduction band, EC, and the valence band, EV,: |EC| < |EF(FB)| < |EV| throughout the depth of the semiconductor. The same constraint applies on the electrode potential scale, where the values are referenced against a common reference electrode: UC(FB) < UF(FB) < UV(FB). Some experimentally determined flat band potentials appear to lie outside these fundamental boundaries. In order to assess the validity of any determined flat band potential, the boundaries set by the conduction band and the valence band must be computed on both scales a priori, where possible. This is accomplished with the aid of an analytical reconstruction of the semiconductor|electrolyte interface in question. To illustrate this approach, we provide a case study based on synthetic hematite, α-Fe2O3. The analysis of this particular semiconductor is motivated by the large variance in the flat band potential values reported in the literature.

Graphical abstract: Constraints to the flat band potential of hematite photo-electrodes

Back to tab navigation

Article information


Submitted
08 Jan 2014
Accepted
16 Jun 2014
First published
26 Jun 2014

Phys. Chem. Chem. Phys., 2014,16, 16176-16186
Article type
Paper
Author version available

Constraints to the flat band potential of hematite photo-electrodes

A. Hankin, J. C. Alexander and G. H. Kelsall, Phys. Chem. Chem. Phys., 2014, 16, 16176
DOI: 10.1039/C4CP00096J

Social activity

Search articles by author

Spotlight

Advertisements