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Issue 3, 2014
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Efficient solar photoelectrolysis by nanoporous Mo:BiVO4 through controlled electron transport

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Abstract

A detailed understanding of doping level, electron diffusion length and coefficient, as well as light capture and charge separation efficiencies in nanoporous Mo-doped BiVO4 (Mo:BiVO4) photoanodes is obtained using photoelectrochemical techniques. Efficient water oxidation is achieved by doping with 1.8% Mo, resulting in a several-fold enhancement in photooxidation rate versus non-doped BiVO4. Two techniques are used to study the effect of Mo doping on the electron transport: (1) an analysis of the front/back illumination ratio of incident photon-to-current efficiency and (2) intensity modulated photocurrent spectroscopy. These techniques show that Mo doping improves the diffusion coefficient four-fold and increases the diffusion length to ca. 300 nm (from 10 nm for the non-doped material), which is also the empirically-determined optimal Mo:BiVO4 film thickness for photoelectrolysis. These films are found to have a 90% charge separation efficiency and an 80% absorbed photon-to-current efficiency, excellent values for metal oxide photoabsorbers. Among the many oxygen evolution catalysts studied, surface modification with iron oxyhydroxide (FeOOH), a simple earth abundant catalyst, dramatically enhances the water oxidation performance of Mo:BiVO4 to an integrated IPCE of 2.41 mA cm−2 and a photocurrent density of 2.77 mA cm−2 in neutral phosphate at 1.23 V vs. RHE.

Graphical abstract: Efficient solar photoelectrolysis by nanoporous Mo:BiVO4 through controlled electron transport

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Supplementary files

Article information


Submitted
30 Oct 2013
Accepted
18 Nov 2013
First published
19 Nov 2013

Phys. Chem. Chem. Phys., 2014,16, 1121-1131
Article type
Paper

Efficient solar photoelectrolysis by nanoporous Mo:BiVO4 through controlled electron transport

J. A. Seabold, K. Zhu and N. R. Neale, Phys. Chem. Chem. Phys., 2014, 16, 1121
DOI: 10.1039/C3CP54356K

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