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Issue 48, 2013
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High-resolution anion photoelectron spectra of TiO2, ZrO2, and HfO2 obtained by slow electron velocity-map imaging

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Abstract

High-resolution anion photoelectron spectra of the Group 4 metal dioxides TiO2, ZrO2, and HfO2 are reported, using slow electron velocity-map imaging (SEVI) combined with ion trapping and cryogenic cooling. The resulting spectra exhibit sub-meV resolution with no congestion from hot bands. Electron affinities are obtained with greater precision than in previous photodetachment experiments, with values of 1.5892(5) eV, 1.6397(5) eV, and 2.1045(5) eV, for TiO2, ZrO2, and HfO2, respectively. We obtain precise values for all of the vibrational frequencies of the neutral [X with combining tilde]1A1 ground states, except for the ν3 mode of HfO2. Weak activity observed in the forbidden ν3 mode for TiO2 and ZrO2 is attributed to Herzberg–Teller coupling to the Ã2B2 excited state.

Graphical abstract: High-resolution anion photoelectron spectra of TiO2−, ZrO2−, and HfO2− obtained by slow electron velocity-map imaging

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Article information


Submitted
26 Sep 2013
Accepted
22 Oct 2013
First published
11 Nov 2013

Phys. Chem. Chem. Phys., 2013,15, 20973-20981
Article type
Paper

High-resolution anion photoelectron spectra of TiO2, ZrO2, and HfO2 obtained by slow electron velocity-map imaging

J. B. Kim, M. L. Weichman and D. M. Neumark, Phys. Chem. Chem. Phys., 2013, 15, 20973
DOI: 10.1039/C3CP54084G

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