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Issue 44, 2012
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Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex

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Abstract

Resonant X-ray Emission Spectroscopy (RXES) is used to characterize the ligand field states of the prototypic self-assembled square-planar complex, [Pt(tpy)Cl]Cl (tpy=2,2′:6′,2′′-terpyridine), and determine the effect of weak metal–metal and π–π interactions on their energy.

Graphical abstract: Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex

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Publication details

The article was received on 18 Jul 2012, accepted on 05 Sep 2012 and first published on 06 Sep 2012


Article type: Communication
DOI: 10.1039/C2CP42451G
Phys. Chem. Chem. Phys., 2012,14, 15278-15281

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    Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex

    C. Garino, E. Gallo, N. Smolentsev, P. Glatzel, R. Gobetto, C. Lamberti, P. J. Sadler and L. Salassa, Phys. Chem. Chem. Phys., 2012, 14, 15278
    DOI: 10.1039/C2CP42451G

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