Kinetics of the iodate reduction by hydrogen peroxide and relation with the Briggs–Rauscher and Bray–Liebhafsky oscillating reactions

Abstract

The iodate reduction by hydrogen peroxide in acidic solutions is part of the Bray–Liebhafsky and Briggs–Rauscher oscillating reactions. At low hydrogen peroxide concentrations, typical of the Bray–Liebhafsky reaction, its rate law is with , 7.8 × 10⁻⁷ (39°), 1.4 × 10⁻⁵ M⁻¹ s⁻¹ (60°) and , 6.2 × 10⁻⁵ (39°), 6.3 × 10⁻⁴ M⁻² s⁻¹ (60°). It is explained by a non-radical mechanism. At high hydrogen peroxide concentrations, typical of the Briggs–Rauscher reaction, a new reaction pathway appears with a rate more than proportional to [H₂O₂]² and nearly independent of [IO₃⁻] > 0.01 M. This pathway is inhibited by scavengers of free radicals. We suggest that it has a radical mechanism starting with IOH + H₂O₂ ⇌ IOOH + H₂O and IOOH+H₂O₂ → IO˙ + H₂O+HOO˙.