LaCoO3 acting as an efficient and robust catalyst for photocatalytic water oxidation with persulfate

Abstract

Cobalt-containing metal oxides [perovskites (LaCoO₃, NdCoO₃, YCoO₃, La_0.7Sr_0.3CoO₃), spinel (Co₃O₄) and wolframite (CoWO₄)] have been examined as catalysts for photocatalytic water oxidation with Na₂S₂O₈ and [Ru(bpy)₃]²⁺ as an electron acceptor and a photosensitizer, respectively. Catalysts with the perovskite structure exhibited higher catalytic activity as compared with the catalysts with the spinel and wolframite structures. LaCoO₃, which stabilizes Co(III) species in the perovskite structure, exhibited the highest catalytic activity in the photocatalytic water oxidation compared with CoWO₄, Co₃O₄ and La_0.7Sr_0.3CoO₃ which contain Co(II) or Co(IV) species in the matrices. The high catalytic reactivity of LaCoO₃ possessing perovskite structure was maintained in NdCoO₃ and YCoO₃ which exclusively contain Co(III) species. Thus, the catalytic activity of Co ions can be controlled by the additional metal ions, which leads to development of highly reactive and robust catalysts for the photocatalytic water oxidation.