SCHEDULED MAINTENANCE
The fast exchange is found to be due to the mismatch between the hydrophobic interaction inside the CB[7] cavity and the ion–dipole/hydrogen-bonding interactions in the port region of the CB[7]. This mismatch also induces the multi-step separation process between guest and CB[7] molecules, as elucidated by molecular dynamics simulation.
![Graphical abstract: Mechanism of the fast exchange between bound and free guests in cucurbit[7]uril–guest systems](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C0CP02349C&imageInfo.ImageIdentifier.Year=2011)
J. Yu, F. Wu, L. Tao, J. Luo and Z. Yu, Phys. Chem. Chem. Phys., 2011, 13, 3638 DOI: 10.1039/C0CP02349C
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