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Issue 35, 2010

Electronic structure of 9-mesityl-10-methylacridinium in ground and excited states: charge-shift mechanism introduced by counter anion shift

Author affiliations

Abstract

The origin of the lowest triplet states—locally excited or charge shifted (TLEvs. TCS)—is a key point in the discussion of the charge shift phenomena of 9-mesityl-10-methylacridinium (see Fukuzumi et al. Phys. Chem. Chem. Phys., 2008, 10, 5159 vs. Benniston et al., Phys. Chem. Chem. Phys., 2008, 10, 5156). Coordination of the anion on the mesityl moiety provides the effective stabilization of the charge-shifted state.

Graphical abstract: Electronic structure of 9-mesityl-10-methylacridinium in ground and excited states: charge-shift mechanism introduced by counter anion shift

Supplementary files

Article information


Submitted
08 May 2010
Accepted
01 Jul 2010
First published
29 Jul 2010

Phys. Chem. Chem. Phys., 2010,12, 10292-10294
Article type
Communication

Electronic structure of 9-mesityl-10-methylacridinium in ground and excited states: charge-shift mechanism introduced by counter anion shift

S. Zilberg, Phys. Chem. Chem. Phys., 2010, 12, 10292 DOI: 10.1039/C0CP00491J

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