Issue 37, 2010
From the journal:

Physical Chemistry Chemical Physics

Dynamics study of the atmospheric reaction involving vibrationally excited O3 with OH

Lei Zhang,*ab   Pingya Luo,a   Rong Zeng,c   Pedro J. S. B. Caridaded  and  António J. C. Varandas*d  

* Corresponding authors

a State Key Laboratory of Oil & Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, Sichuan, P. R. China
E-mail: zgc166929@sohu.com

b School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, Sichuan, P. R. China

c School of Information Science & Technology, Southwest Jiaotong University, Chengdu 610031, Sichuan, P.R. China

d Departamento de Química, Universidade de Coimbra, 3004-535 Coimbra, Portugal
E-mail: varandas@qtvs1.qui.uc.pt

Abstract

We investigate the title atmospheric reaction of highly excited O3 with vibrationally cold OH. Particular attention will be paid to initial vibrational energies of O3 between 9 and 21 kcal mol−1. The calculations employ the quasiclassical trajectory method and the realistic double many-body expansion potential energy surface for HO4(2A). Many aspects of the title process are presented. It is found that it may not be possible to ignore this process when studying the stratospheric ozone budget.

Graphical abstract: Dynamics study of the atmospheric reaction involving vibrationally excited O3 with OH

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B927542H
Article type
Paper
Submitted
05 Jan 2010
Accepted
11 May 2010
First published
02 Aug 2010

Phys. Chem. Chem. Phys., 2010,12, 11362-11370

Permissions

Request permissions

Dynamics study of the atmospheric reaction involving vibrationally excited O3 with OH

L. Zhang, P. Luo, R. Zeng, P. J. S. B. Caridade and A. J. C. Varandas, Phys. Chem. Chem. Phys., 2010, 12, 11362 DOI: 10.1039/B927542H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements