Issue 11, 2010
From the journal:

Physical Chemistry Chemical Physics

Orientation dependence in the four-atom reaction of OH + HBr using the single-state oriented OH radical beam

Po-Yu Tsai,†a   Dock-Chil Che,*a   Masaaki Nakamura,a   King-Chuen Linb  and  Toshio Kasaia  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan
E-mail: che@chem.sci.osaka-u.ac.jp

b Department of Chemistry, National Taiwan University, Taipei 106, and Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan

Abstract

The orientation dependence for the Br atom formation in the reaction of the oriented OH radicals with HBr molecules at 0.26 eV collision energy has been observed for the first time using the hexapole electric field, and we found that the reaction cross-section for O-end attack is more favorable than that for H-end attack by a factor of 3.4 ± 2.3.

Graphical abstract: Orientation dependence in the four-atom reaction of OH + HBr using the single-state oriented OH radical beam

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Article information

DOI
https://doi.org/10.1039/B923934K
Article type
Communication
Submitted
17 Nov 2009
Accepted
14 Jan 2010
First published
02 Feb 2010

Phys. Chem. Chem. Phys., 2010,12, 2532-2534

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Orientation dependence in the four-atom reaction of OH + HBr using the single-state oriented OH radical beam

P. Tsai, D. Che, M. Nakamura, K. Lin and T. Kasai, Phys. Chem. Chem. Phys., 2010, 12, 2532 DOI: 10.1039/B923934K

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