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Issue 31, 2010
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Hydrophilicity, the major determining factor influencing the solvation environment of protic ionic liquids

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Abstract

The study of solubility of 4-nitroaniline and its N,N-diethyl derivative in ionic liquids (ILs) of varying water content has shown that it is the interaction between water and the ILs’ ions, and not with the solute, that is the most important factor determining the solute's preferential hydration parameter and thus the solvation shell structure.

Graphical abstract: Hydrophilicity, the major determining factor influencing the solvation environment of protic ionic liquids

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Publication details

The article was received on 16 Sep 2009, accepted on 29 Apr 2010 and first published on 18 Jun 2010


Article type: Paper
DOI: 10.1039/B919348K
Citation: Phys. Chem. Chem. Phys., 2010,12, 9063-9066

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    Hydrophilicity, the major determining factor influencing the solvation environment of protic ionic liquids

    L. Wright, M. W. Sanders, L. Tate, G. Fairless, L. Crowhurst, N. C. Bruce, A. J. Walker, G. A. Hembury and S. Shimizu, Phys. Chem. Chem. Phys., 2010, 12, 9063
    DOI: 10.1039/B919348K

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