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Issue 42, 2009
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A novel pulse isotopic exchange technique for rapid determination of the oxygen surface exchange rate of oxide ion conductors

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Abstract

We demonstrate the use of a novel pulse 18O–16O isotopic exchange technique for the rapid determination of the oxygen surface exchange rate of oxide ion conductors while simultaneously providing insight into the mechanism of the oxygen exchange reaction, which contributes to the efficient development of devices incorporating these solids, such as solid oxide fuel cells and oxygen transport membranes.

Graphical abstract: A novel pulse isotopic exchange technique for rapid determination of the oxygen surface exchange rate of oxide ion conductors

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Publication details

The article was received on 26 Jun 2009, accepted on 18 Aug 2009 and first published on 26 Aug 2009


Article type: Communication
DOI: 10.1039/B912712G
Phys. Chem. Chem. Phys., 2009,11, 9640-9643

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    A novel pulse isotopic exchange technique for rapid determination of the oxygen surface exchange rate of oxide ion conductors

    H. J. M. Bouwmeester, C. Song, J. Zhu, J. Yi, M. van Sint Annaland and B. A. Boukamp, Phys. Chem. Chem. Phys., 2009, 11, 9640
    DOI: 10.1039/B912712G

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