Issue 31, 2009
From the journal:

Physical Chemistry Chemical Physics

A W-band pulsed EPR/ENDOR study of CoIIS4 coordination in the Co[(SPPh2)(SPiPr2)N]2 complex

Silvia Sottini,*a   Guinevere Mathies,a   Peter Gast,a   Dimitrios Maganas,b   Panayotis Kyritsisb  and  Edgar J.J. Groenena  

* Corresponding authors

a Huygens Laboratory, Leiden University Niels Bohrweg 2, 2333 CA Leiden, The Netherlands
E-mail: sottini@molphys.leidenuniv.nl
Fax: +31 (0)71 527 5819
Tel: +31 (0)71 527 5907

b Inorganic Chemistry Laboratory, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis, GR-157 71 Athens, Greece
E-mail: Kyritsis@chem.uoa.gr
Fax: +30 210 727 4782
Tel: +30 210 727 4268

Abstract

Spin-echo detection at 95 GHz enables an electron-paramagnetic-resonance study of a cobalt complex with a bio-mimetic coordination of the transition metal by four sulfur atoms. A magnetically diluted single crystal of the complex has been investigated in great detail. Electron-nuclear double-resonance signals were observed of ligand nuclei and complete hyperfine tensors of the distinct phosphorus nuclei were derived, assigned and discussed.

Graphical abstract: A W-band pulsed EPR/ENDOR study of CoIIS4 coordination in the Co[(SPPh2)(SPiPr2)N]2 complex

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Article information

DOI
https://doi.org/10.1039/B905726A
Article type
Paper
Submitted
23 Mar 2009
Accepted
18 Jun 2009
First published
08 Jul 2009

Phys. Chem. Chem. Phys., 2009,11, 6727-6732

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A W-band pulsed EPR/ENDOR study of CoIIS4 coordination in the Co[(SPPh2)(SPiPr2)N]2 complex

S. Sottini, G. Mathies, P. Gast, D. Maganas, P. Kyritsis and E. J.J. Groenen, Phys. Chem. Chem. Phys., 2009, 11, 6727 DOI: 10.1039/B905726A

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