Issue 1, 2008
From the journal:

Physical Chemistry Chemical Physics

Hydrogen transfer from guest molecule to radical in adjacent hydrate-cages

Kazunari Ohgaki,*a   Kentaro Nakatsuji,a   Kei Takeya,a   Atsushi Tanib  and  Takeshi Sugaharaa  

* Corresponding authors

a Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka, Japan
E-mail: ohgaki@cheng.es.osaka-u.ac.jp
Fax: +81 (0)6 6850 6290
Tel: +81 (0)6 6850 6290

b Department of Earth and Space Science, Graduate School of Science, Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka, Japan
E-mail: atani@ess.sci.osaka-u.ac.jp

Abstract

Electron spin resonance measurement of gamma-ray-irradiated propane hydrates shows that the normal propyl radical withdraws hydrogen from the adjacent propane molecule through the hexagonal planes of the hydrate cage without water molecule bridging.

Graphical abstract: Hydrogen transfer from guest molecule to radical in adjacent hydrate-cages

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Article information

DOI
https://doi.org/10.1039/B715284A
Article type
Communication
Submitted
04 Oct 2007
Accepted
12 Nov 2007
First published
20 Nov 2007

Phys. Chem. Chem. Phys., 2008,10, 80-82

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Hydrogen transfer from guest molecule to radical in adjacent hydrate-cages

K. Ohgaki, K. Nakatsuji, K. Takeya, A. Tani and T. Sugahara, Phys. Chem. Chem. Phys., 2008, 10, 80 DOI: 10.1039/B715284A

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