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Issue 38, 2006
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Induced hyper-valence of carbon in metal:fluorocarbon complexes

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Abstract

Charge-transfer in combination with geometric features induces a pentavalent state of the carbon atom in metastable super-fluorinated alkali-metal compounds, M:C2F7 (M = K to Cs).

Graphical abstract: Induced hyper-valence of carbon in metal:fluorocarbon complexes

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Article information


Submitted
20 Jun 2006
Accepted
23 Aug 2006
First published
01 Sep 2006

Phys. Chem. Chem. Phys., 2006,8, 4402-4404
Article type
Communication

Induced hyper-valence of carbon in metal:fluorocarbon complexes

F. Y. Naumkin, Phys. Chem. Chem. Phys., 2006, 8, 4402
DOI: 10.1039/B608712D

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