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Issue 26, 2006
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Muon spin relaxation study of Zr(H2PO4)(PO4)·2H2O

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Abstract

Muon spin relaxation has been used to study the muon dynamics in the layered zirconium phosphate Zr(H2PO4)(PO4)·2H2O as a function of temperature. Radiofrequency decoupling was used to establish the origin of the local dipolar field as coupling with 1H spins. Muons were trapped at two sites, one identified as HMuO and the other consistent with PO–Mu on the basis of their zero-field second moments. Although a small decrease in the local nuclear dipolar field was seen with temperature, the muons remained essentially static over the temperature range 20–300 K.

Graphical abstract: Muon spin relaxation study of Zr(H2PO4)(PO4)·2H2O

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Article information


Submitted
16 Mar 2006
Accepted
25 Apr 2006
First published
01 Jun 2006

Phys. Chem. Chem. Phys., 2006,8, 3094-3098
Article type
Paper

Muon spin relaxation study of Zr(H2PO4)(PO4)·2H2O

N. J. Clayden and S. P. Cottrell, Phys. Chem. Chem. Phys., 2006, 8, 3094
DOI: 10.1039/B603913H

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