Issue 16, 2006
From the journal:

Physical Chemistry Chemical Physics

Size of neutral argon clusters from core-level photoelectron spectroscopy†

H. Bergersen,*a   M. Abu-samha,b   J. Harnes,b   O. Björneholm,a   S. Svensson,a   L. J. Sæthreb  and  K. J. Børve*b  

* Corresponding authors

a Department of Physics, Uppsala University, Box 530, Uppsala, Sweden
E-mail: henrik.bergersen@fysik.uu.se

b Department of Chemistry, University of Bergen, Bergen, Norway
E-mail: knut.borve@kj.uib.no

Abstract

Theoretical models of lineshapes in Ar2p photoionization spectra have been calculated for free, neutral argon clusters of different sizes. The lineshape models are fitted to experimental spectra and used to estimate the mean cluster size realized in the experiment. The results indicate that size estimators working from stagnation conditions [R. Karnbach, M. Joppien, J. Stapelfeldt, J. Wörmer and T.Möller, Rev. Sci. Instrum., 1993, 64, 2838] may underestimate the mean cluster size.

Graphical abstract: Size of neutral argon clusters from core-level photoelectron spectroscopy

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Article information

DOI
https://doi.org/10.1039/B515554A
Article type
Paper
Submitted
02 Nov 2005
Accepted
18 Jan 2006
First published
08 Feb 2006

Phys. Chem. Chem. Phys., 2006,8, 1891-1898

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Size of neutral argon clusters from core-level photoelectron spectroscopy

H. Bergersen, M. Abu-samha, J. Harnes, O. Björneholm, S. Svensson, L. J. Sæthre and K. J. Børve, Phys. Chem. Chem. Phys., 2006, 8, 1891 DOI: 10.1039/B515554A

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