Generalised Maxwell-Garnett equation: application to electrical and chemical transport†
Abstract
In this paper we discuss the implementation of different equilibrium concentrations in each of the phases into the Maxwell-Garnett effective medium formula for diffusion in heterogeneous media. We put the derivation given by Kalnin et al., J. Phys. Chem. Solids, 2002, 63, 449, on safer grounds and extend it to non-dilute carrier concentrations. The relation to Maxwell’s