Issue 16, 2004

Spectral diffusion of the anti-symmetric stretching mode of azide ion in a reverse micelle studied by infrared three-pulse photon echo method

Abstract

Fluctuation of the transition frequency of the anti-symmetric stretching mode of the azide ion in a nonionic reverse micelle was studied by infrared three-pulse photon echo method. The time correlation function of the frequency fluctuation has three components. It is found that the contribution of the static component is much larger than that in the bulk water, while the other two components with faster time constants are similar to those in the bulk.

Graphical abstract: Spectral diffusion of the anti-symmetric stretching mode of azide ion in a reverse micelle studied by infrared three-pulse photon echo method

Article information

Article type
Communication
Submitted
11 May 2004
Accepted
08 Jul 2004
First published
16 Jul 2004

Phys. Chem. Chem. Phys., 2004,6, 4074-4077

Spectral diffusion of the anti-symmetric stretching mode of azide ion in a reverse micelle studied by infrared three-pulse photon echo method

H. Maekawa, K. Ohta and K. Tominaga, Phys. Chem. Chem. Phys., 2004, 6, 4074 DOI: 10.1039/B407017H

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