Sorbate-induced changes in the framework of the titanosilicate ETS-10 as detected by 29Si MAS NMRspectroscopy and X-ray powder diffraction
Abstract
The framework of ETS-10 undergoes reversible structural changes upon dehydration and rehydration. Pronounced differences in the 29Si MAS NMR spectra clearly indicate rearrangements in the local environment, while the X-ray powder diffraction patterns provide evidence for a long-range effect of the guest/host interaction. A detailed analysis of the structural changes by