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Issue 11, 2002
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The water dimer in a too tight matrix cage

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Abstract

When an argon matrix containing hydrogen peroxide dimer is irradiated with 266 nm radiation from a YAG laser, water forms. Some of it is formed as monomer but the main part is formed as dimer. The photogenerated water dimer is formed together with an oxygen molecule in the cage of the parent hydrogen peroxide dimer and the dimer bands are shifted from their normal positions indicating that the cage severely perturbs the product structure.

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Publication details

The article was received on 19 Dec 2001, accepted on 06 Feb 2002 and first published on 23 Apr 2002


Article type: Paper
DOI: 10.1039/B111588J
Phys. Chem. Chem. Phys., 2002,4, 2140-2143

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    The water dimer in a too tight matrix cage

    A. Engdahl and B. Nelander, Phys. Chem. Chem. Phys., 2002, 4, 2140
    DOI: 10.1039/B111588J

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