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Issue 20, 2000
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A mapping equation of state: development for the dipolar hard sphere fluid

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Abstract

A new generalised equation of state is proposed and applied to a dipolar hard sphere fluid. This general equation of state has been successfully employed earlier for modelling a hard sphere chain fluid. It is shown that it is possible to map complicated equations which are derived by perturbation approaches on this simple equation. In addition different applications of the c-factor approach are discussed and implemented in the proposed equation of state. Furthermore, a simplified version of a molecular based dispersion term is proposed. The result is a simple fourth-order equation of state for molecular fluids.

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Publication details

The article was received on 28 Jun 2000, accepted on 14 Aug 2000 and first published on 27 Sep 2000


Article type: Paper
DOI: 10.1039/B005196I
Phys. Chem. Chem. Phys., 2000,2, 4734-4739

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    A mapping equation of state: development for the dipolar hard sphere fluid

    L. V. Yelash and T. Kraska, Phys. Chem. Chem. Phys., 2000, 2, 4734
    DOI: 10.1039/B005196I

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