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Issue 22, 2019

Solvent-induced SC–SC transformation within the ZnII–triazole system: a promising MnO4 selective luminescent probe

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Abstract

A series of coordination polymers based on the ligand tris(4-(1H-1,2,4-triazol-1-yl)phenyl)amine (TTPA) have been developed. Amongst these, complexation with Zn2+ results in a 1D ladder complex. The solvent-induced SC–SC transformation within the Zn2+–triazole system has resulted in a unique solvate, generating {[Zn(TTPA)(NO3)2]·2CHBr3}n (4a). Compound 4a was tested for both cation and anion capture of important industrial pollutants. The luminescence properties of 4a indicated that it could be considered as a new triazole based selective luminescent probe for both Pb2+ and MnO4.

Graphical abstract: Solvent-induced SC–SC transformation within the ZnII–triazole system: a promising MnO4− selective luminescent probe

Supplementary files

Article information


Submitted
05 Mar 2019
Accepted
09 May 2019
First published
13 May 2019

CrystEngComm, 2019,21, 3390-3394
Article type
Communication

Solvent-induced SC–SC transformation within the ZnII–triazole system: a promising MnO4 selective luminescent probe

L. Cheng, C. Xue, Y. Wang, D. Yang, Y. Zhang, Y. Gao and G. S. Day, CrystEngComm, 2019, 21, 3390 DOI: 10.1039/C9CE00312F

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